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閲戝睘鐨勮厫铓鏃犲涓嶅湪銆傛牴鎹編鍥藉叏鍥借厫铓宸ョ▼甯堝崗浼?/span>2016騫寸殑涓浠芥姤鍛婏紙http://impact.nace.org/documents/Nace-International-Report.pdf錛?/span>錛岃厫铓鐜拌薄姣忓勾鍦ㄥ叏鐞冮犳垚綰?/span>2.5涓囦嚎緹庡厓鐨勭粡嫻庢崯澶憋紝榪欑浉褰撲簬鍏ㄧ悆GDP鎬誨拰鐨?.4%錛堜互2013騫存暟鎹錛夈傚叾涓紝鐢?shù)鍋惰厫铓鏄竴縐嶉潪甯稿父瑙佺殑鐜拌薄銆傚綋涓ょ涓嶅悓閲戝睘鐩鎬簰鎺ヨЕ鏃訛紝鐢變簬鍖栧鍔胯兘鐨勫樊寮傦紝涓ょ閲戝睘闂村艦鎴愬師鐢墊睜錛屼嬌寰楁洿媧繪臣鐨勯噾灞炶鍔犻熻厫铓銆傚綋鐒訛紝榪欑鏁堝簲涔熶笉鎬繪槸鏈夊鐨勩備緥濡傚湪鑸硅埗鍒墮犱腑錛屽父甯鎬細浣跨敤閿屾垨閾濆潡浣滀負鐗虹壊鐢墊瀬鏉ヤ繚鎶ら挗緇撴瀯鐨勮埞浣撲笉鍙楁搗姘寸殑渚佃殌銆?/span>


鍦ㄧ撼綾蟲潗鏂欓鍩燂紝鍏鋒湁杈冧負澶嶆潅緇撴瀯鐨勫閲戝睘綰崇背棰楃矑宸茬粡鍦ㄨ澶氶鍩熷睍鐜板嚭浜嗗簲鐢ㄥ墠鏅傝澶氱撼綾蟲潗鏂欏寘鍚笉鍚岄噾灞炴瀯鎴愮殑澶氫釜緇勬垚閮ㄥ垎銆傚洜姝わ紝榪欑鐢?shù)鍋惰厫铓鏁堝簲鍙婄浉鍏崇殑鐗╄川浼犺緭鍙兘涔熷湪綰崇背鏉愭枡涓駭鐢熼噸瑕佸獎鍝嶃備簨瀹炰笂錛岀撼綾崇矑瀛愬湪鍖呮嫭錛堢數(shù)鍖栧錛夊偓鍖栥佷紶鎰熴佽瘖鐤楃瓑璇稿搴旂敤涓父甯告毚闇插湪寮虹數(shù)瑙ｈ川鐜涓傜劧鑰岀洰鍓嶄負姝紝榪樻湭鏈夊寮傝川緇撴瀯綰崇背綺掑瓙鐨勭數(shù)鍋惰厫铓鐨勭郴緇熸х爺絀躲?/span> 榪戞湡錛岀編鍥借タ鍖楀ぇ瀛?/span>Chad Mirkin銆?/span>Vinayak Dravid鏁欐巿鍥㈤槦緇撳悎鎵弿鎺㈤拡鑱氬悎鐗╃撼綾沖弽搴斿櫒鍜屽師浣嶆壂鎻忛忓皠鐢?shù)闀滄妧鏈彮紺轟簡寮傝川緇撴瀯綰崇背綺掑瓙鍦ㄦ按鐩稿拰姘磋捀姘旂浉鐜涓殑鑵愯殌妯″紡銆傜爺絀跺洟闃熷埄鐢ㄨ仛鍚堢墿綰崇背鍙嶅簲鍣ㄥ悎鎴愪簡涓緋誨垪璐甸噾灞?/span>-闈炶吹閲戝睘寮傝川緇撴瀯綰崇背綺掑瓙錛屽茍鎺㈢儲浜嗗叾鍦ㄦ按鐩告憾娑蹭腑鐨勭ǔ瀹氭с傝繘涓姝ワ紝璇ュ洟闃熷湪娑茬浉鍜屾皵鐩稿師浣嶇數(shù)闀滄牱鍝佹潌鐨勭獥鍙ｈ姱鐗囦笂鐩存帴鍚堟垚浜嗙撼綾沖弽搴斿櫒闃靛垪騫跺緱鍒板紓璐ㄧ粨鏋勭撼綾崇矑瀛愶紝鍙戠幇Ag-Cu綰崇背綺掑瓙鍦ㄦ按鍜屾按钂告皵鐜涓潎閬靛驚涓縐嶄袱姝ュ弽搴旀満鍒躲傚湪絎竴闃舵錛?/span>Cu浣滀負鏇存椿娉肩殑閲戝睘琚紭鍏堝埢铓錛岃屽埢铓浜х墿紕庣墖鍖栨帀钀斤紱褰?/span>Cu瀹屽叏鐗虹壊鍚庯紝Ag鎵嶄細蹇熻姘у寲銆傝宸ヤ綔榪涗竴姝ュ彂鐜頒簡涓縐嶅彲浠ュ寮鴻繖縐嶅紓璐ㄧ撼綾崇粨鏋勬姉鑵愯殌紼沖畾鎬х殑鏂規(guī)硶銆傚湪姘╃瓑紱誨瓙娓呮礂鍚庯紝Cu琛ㄩ潰鐨勬棤瀹氬艦姘у寲灞傚彲鑳借漿鍙樹負鏇村姞鑷村瘑鐨勫３灞傦紝闃婚殧浜嗙數(shù)鍋惰厫铓鎵闇鐨勭數(shù)鑽峰拰鐗╄川杞Щ銆傝繖浣垮緱Ag-Cu綰崇背綺掑瓙鐨勭ǔ瀹氭ф樉钁楁彁楂樸傝宸ヤ綔鍙兘涓虹撼綾崇矑瀛愬湪搴旂敤鍜屽疄闄呭伐浣滅幆澧冧腑鐨勭ǔ瀹氭у拰褰㈣矊杞彉鏈哄埗鐮旂┒寮杈熶簡閬撹礬銆?/span>



鐢變袱縐嶄笉鍚岄噾灞炴帴瑙︿駭鐢熺殑鐢?shù)鍋惰厫铓錛氬ぇ鍧楁潗鏂欙紙涓婏級鍜?/span>綰崇背綺掑瓙錛堜笅錛?/span>


鍙岄噾灞?/span>綰崇背棰楃矑鍦ㄦ按鐩哥幆澧冧腑鐨勮厫铓銆傦紙A錛変笉鍚屽弻閲戝睘綰崇背綺掑瓙鐨勭數(shù)鍖栧紼沖畾鎬ф樉钁椾笉鍚屻傦紙B鈥揇錛堿u-Cu鍚堥噾綰崇背綺掑瓙鐨勫厓绱犲垎甯冨湪 0.5 M HCl涓蹈娉″墠鍚庯紙B銆丆錛夋病鏈夋樉钁楃殑鍙樺寲錛屽畾閲忓垎鏋愮粨鏋滄樉紺篊u鍙戠敓浜嗗皯閲忔祦澶憋紝浣嗗茍鏈畬鍏ㄨ鑵愯殌錛圖錛夈傦紙E銆丗錛堿u-Co綰崇背綺掑瓙鍦ㄥ幓紱誨瓙姘翠腑嫻告場鍓嶅悗褰㈣矊銆侰o閮ㄥ垎鑳藉琚畬鍏ㄥ埢铓銆傦紙G錛変竴棰楀湪鍘葷瀛愭按涓蹈娉¤繃鐨凙g-Cu綰崇背綺掑瓙錛岃緇撴灉鏄劇ずAg鏈鑵愯殌錛岃屾畫鐣欑殑Cu鍏冪礌鑱氶泦鍦ㄤ竴涓笉鍚岀殑鍖哄煙銆?/span>


鑷敱鍩哄姞閫熺殑娑茬浉鍘熶綅鑵愯殌鐮旂┒銆?/span>錛圓銆丅錛夌撼綾崇矑瀛愰樀鍒楄礋杞藉湪鍦ㄧ獥鍙ｈ姱鐗囦笂錛涘湪娑蹭綋妲戒腑錛屼竴涓皵娉″彈鎺х敓鎴愪互鍑忓皯鐢?shù)瀛愭暎灏勻q舵彁楂樻垚鍍忎俊鍣瘮鍜屽垎杈ㄧ巼銆傦紙C銆丏錛夊畾閲忓垎鏋愪竴棰桝g-Cu綰崇背綺掑瓙鐨勫師浣嶅埢铓榪囩▼鏄劇ず璇ヨ繃紼嬬敱涓や釜姝ラ緇勬垚錛氱涓姝u姘у寲浜х墿紕庣墖鍖栨帀钀斤紝絎簩姝g鍦–u瀹屽叏鍙嶅簲鍚庡揩閫熸憾瑙ｃ傦紙E錛夊簭鍒楀師浣嶇數(shù)闀滃浘鍍忋?/span>


鑷敱鍩哄姞閫熺殑钂告苯鐩稿師浣嶈厫铓鐮旂┒銆?/span>錛圓錛夊湪鍘熶綅姘旂浉鏍峰搧鏉嗕腑寮曞叆杈冧綆鍘嬪己鐨勭函姘磋捀姘斾互鐮旂┒綰崇背綺掑瓙鍦ㄨ捀姹界浉涓殑鑵愯殌榪囩▼銆傜浉姣旀恫鐩哥幆澧冿紝钂告苯鐩哥殑鐮旂┒鍙互鍙栧緱鏇撮珮鐨勪俊鍣瘮銆佸垎杈ㄧ巼錛屽茍涓嶅彈娑叉祦寮曡搗鐨勭墿璐ㄤ紶杈撶殑騫叉壈銆傦紙B銆丆錛夊湪姘旂浉紿楀彛鑺墖涓婃垚鍔熷悎鎴愪簡鑱氬悎鐗╃撼綾沖弽搴斿櫒闃靛垪騫惰繘鑰屽緱鍒扮撼綾崇矑瀛愰樀鍒椼傦紙C錛夎捀姹界浉涓殑Ag-Cu綰崇背綺掑瓙涔熼伒寰被浼肩殑涓ゆ鍙嶅簲妯″紡銆傚拰娑茬浉涓嶅悓鐨勬槸錛岃瀹為獙涓病鏈夎瀵熷埌娑蹭綋鐩哥殑褰㈡垚錛屽洜姝ょ數(shù)鍋惰厫铓鎵闇鐨勭瀛愪紶杈撳彲鑳芥槸閫氳繃綰崇背灝哄害鐨勮〃闈㈡墿鏁ｅ彂鐢熺殑銆?/span>


琛ㄩ潰緇撴灉瀵笰g-Cu綰崇背綺掑瓙鑵愯殌琛屼負鐨勫獎鍝嶃?/span>錛圓銆丅錛夊湪姘╃瓑紱誨瓙娓呮礂鍚庯紝Ag-Cu綰崇背綺掑瓙鍦ㄦ按鐩鎬腑鐨勬姉鑵愯殌紼沖畾鎬ф樉钁楁彁鍗囥傦紙C銆丏錛夊湪鍘熶綅钂告苯鐩稿疄楠屼腑錛岀粡榪囨癌絳夌瀛愭竻媧楀悗鐨凙g-Cu綰崇背綺掑瓙涓嶅啀閬靛驚鍏圕u鍚嶢g鐨勫埢铓瑙勫緥銆傦紙E鈥揋錛夐珮鍒嗚鯨鎵弿閫忓皠鐢?shù)闀溇l撴灉鏄劇ず錛屾癌絳夌瀛愭竻媧楀悗鐨凜u琛ㄩ潰褰㈡垚浜嗘櫠鎬佺殑鑷村瘑姘у寲澹沖眰銆傝澹沖眰鍙兘闃婚殧浜嗙數(shù)鍋惰厫铓鎵闇鐨勭數(shù)鑽峰拰鐗╄川浼犺緭錛屽洜姝ら樆姝簡Cu鐨勮厫铓銆?/span>


璇ュ伐浣滆繎鏃ュ彂琛ㄥ湪銆婂厛榪涘姛鑳芥潗鏂欍嬶細Galvanic Transformation Dynamics in Heterostructured Nanoparticles, Advanced Functional Materials, DOI: 10.1002/adfm.202105866錛涚涓浣滆呬負緹庡浗瑗垮寳澶у鍗氬＋鐮旂┒鐢熸潨绔炴潐銆?/span>


鐩稿叧閾炬帴

https://onlinelibrary.wiley.com/doi/10.1002/adfm.202105866

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