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Benzene-cored fluorophors with TPE peripheries: facile synthesis, crystallization-induced blue-shifted emission, and efficient blue luminogens for non-doped OLEDs  
Benzene-cored fluorophors with TPE peripheries: facile synthesis, crystallization-induced blue-shifted emission, and efficient blue luminogens for non-doped OLEDs
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關鍵詞: TPE  blue  luminogens  OLEDs  
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In this paper, three benzene-cored fluorophors with TPE moiety peripheries (PhTPE, Ph2TPE and Ph3TPE), are synthesized and their thermal, optical and electronic properties are investigated. All of them are nearly non-emissive when readily dissolved in solution but become highly emissive in the aggregate state, making them promising candidates for optoelectronic materials. Non-doped OLEDs with these luminogens as emissive layers exhibit sky-blue to deep blue emissions from 488 to 457 nm, owing to the twisted conformation between the benzene core and TPE units.
上傳人: lizhen
上傳時間: 2014-02-11 22:39:48
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